资源类型

期刊论文 43

年份

2023 1

2022 2

2020 6

2019 2

2018 1

2017 4

2016 2

2015 4

2014 6

2013 1

2012 3

2011 1

2010 2

2009 6

2008 1

2007 1

展开 ︾

关键词

厌氧消化，生物固体，污染，甲基苯丙胺，吸附 1

吸附 1

响应面分析法 1

等温线 1

铅 1

香蕉假茎 1

展开 ︾

检索范围：

排序： 展示方式：

Performance and mechanism for cadmium and lead adsorption from water and soil by corn straw biochar

Tong Chi,Jiane Zuo,Fenglin Liu

《环境科学与工程前沿（英文）》 2017年 第11卷 第2期 doi: 10.1007/s11783-017-0921-y

摘要： Corn straw biochar prepared under 400 °C was the best Cd and Pb adsorption capacity Maximum adsorption capacity of Cd and Pb were 43.48 and 22.73 mg·g , respectively The dominant mechanism of Cd and Pb adsorption was precipitation Biochar could reduce the bioavailability of heavy metals when mixed with soil Cadmium (Cd) and lead (Pb) in water and soil could be adsorbed by biochar produced from corn straw. Biochar pyrolyzed under 400°C for 2 h could reach the ideal removal efficiencies (99.24% and 98.62% for Cd and Pb, respectively) from water with the biochar dosage of 20 g·L and initial concentration of 20 mg·L . The pH value of 4–7 was the optimal range for adsorption reaction. The adsorption mechanism was discussed on the basis of a range of characterizations, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and Raman analysis; it was concluded as surface complexation with active sorption sites (-OH, -COO-), coordination with π electrons (C= C, C= O) and precipitation with inorganic anions (OH , CO , SO ) for both Cd and Pb. The sorption isotherms fit Langmuir model rather than Freundlich model, and the saturated sorption capacities for Cd and Pb were 38.91 mg·g and 28.99 mg·g , respectively. When mixed with soil, biochar could effectively increase alkalinity and reduce bioavailability of heavy metals. Thus, biochar derived from corn straw would be a green material for both removal of heavy metals and amelioration of soil.

关键词： Corn straw     Biochar     Heavy metals     Sorption isotherm     Bioavailability    

HTML PDF 收藏

Major applications of heat pipe and its advances coupled with sorption system: a review

Yang YU, Guoliang AN, Liwei WANG

《能源前沿（英文）》 2019年 第13卷 第1期   页码 172-184 doi: 10.1007/s11708-019-0610-6

摘要： Heat pipe utilizes continuous phase change process within a small temperature drop to achieve high thermal conductivity. For decades, heat pipes coupled with novel emerging technologies and methods (using nanofluids and self-rewetting fluids) have been highly appreciated, along with which a number of advances have taken place. In addition to some typical applications of thermal control and heat recovery, the heat pipe technology combined with the sorption technology could efficiently improve the heat and mass transfer performance of sorption systems for heating, cooling and cogeneration. However, almost all existing studies on this combination or integration have not concentrated on the principle of the sorption technology with acting as the heat pipe technology for continuous heat transfer. This paper presents an overview of the emerging working fluids, the major applications of heat pipe, and the advances in heat pipe type sorption system. Besides, the ongoing and perspectives of the solid sorption heat pipe are presented, expecting to serve as useful guides for further investigations and new research potentials.

关键词： heat pipe     sorption system     heat transfer     solid sorption heat pipe    

HTML PDF 收藏

Preparation of adsorptive nanoporous membrane using powder activated carbon: Isotherm and thermodynamic

Majid Peyravi

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 673-687 doi: 10.1007/s11705-019-1800-9

摘要： Adsorptive polyethesulfone (PES) membranes were prepared by intercalation of powder activated carbon (PAC) with and without functionalization. Accordingly, PAC was aminated with 1,5-diamino-2-methylpentane, and the physicochemical properties of the functionalized PAC were analyzed. Intercalation of PAC within the PES scaffold changed the porosity and mean pore size of the aminated membrane (AC-NH ) from 52.6% to 92.5% and from 22.6 nm to 3.5 nm, respectively. The effect of temperature on the performance of the modified membranes was monitored by the flux and chemical oxygen demand (COD) removal of leachate. At ambient temperature, the COD removal of the neat, AC-containing, and AC-NH membranes was 47%, 52%, and 58.5%, respectively. A similar increment was obtained for the membrane flux, which was due to the synergistic effect of the high porosity and large number of hydrophilic functional groups. The experimental leachate adsorption data were analyzed by Langmuir, Freundlich, and Dubinin- Radushkevich isotherm models. For all membranes, the significant thermodynamic parameters ( , , and ) were calculated and compared. The isosteric heat of adsorption was lower than 80 kJ∙mol , indicating that the interaction between the membranes and the leachate is mainly physical, involving weak van der Waals forces.

关键词： amine functionality     nanoporous membrane     adsorption isotherm     thermodynamic parameters     landfill leachate    

HTML PDF 收藏

Sorption mechanisms of diphenylarsinic acid on natural magnetite and siderite: Evidence from sorption

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1547-2

摘要：

• DPAA sorption followed pseudo-secondary and intra-particle diffusion models.

关键词： Diphenylarsinic acid (DPAA)     Sorption     Magnetite     Siderite     Sequential extraction     EXAFS    

HTML PDF 收藏

Thermodynamic study on dynamic water and organic vapor sorption on amorphous valnemulin hydrochloride

Jinbo OUYANG, Jingkang WANG, Yongli WANG, Qiuxiang YIN, Hongxun HAO

《化学科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 94-104 doi: 10.1007/s11705-015-1460-3

摘要： The sorption of water and organic vapors on valnemulin hydrochloride was determined by dynamic vapor sorption at 25 °C. The adsorption-desorption behavior of water vapor and a series of organic vapors was investigated to probe the structural changes in valnemulin hydrochloride before and after sorption. The isothermal adsorption equilibrium data was evaluated using Guggenheim-Anderson-deBoer (GAB) and Brunauer-Emmett-Teller (BET) models. The BET model is applicable only at low relative pressures (0.1≤RP≤0.4) while the GAB model is applicable in the whole range of RPs (0.1≤RP≤0.9). The sorption kinetics at high RPs was determined by fitting the sorption data to the Avrami equation and the sorption content time relationship could be predicted by the Avrami equation. Finally, the possible sorption mechanism of valnemulin hydrochloride was also discussed.

关键词： valnemulin hydrochloride     water vapor     organic vapors     sorption     kinetics    

HTML PDF 收藏

Simulation and experiments on a solid sorption combined cooling and power system driven by the exhaust

Peng GAO, Liwei WANG, Ruzhu WANG, Yang YU

《能源前沿（英文）》 2017年 第11卷 第4期   页码 516-526 doi: 10.1007/s11708-017-0511-5

摘要： A solid sorption combined cooling and power system driven by exhaust waste heat is proposed, which consists of a MnCl sorption bed, a CaCl sorption bed, an evaporator, a condenser, an expansion valve, and a scroll expander, and ammonia is chosen as the working fluid. First, the theoretical model of the system is established, and the partitioning calculation method is proposed for sorption beds. Next, the experimental system is established, and experimental results show that the refrigerating capacity at the refrigerating temperature of –10°C and the resorption time of 30 min is 1.95 kW, and the shaft power is 109.2 W. The system can provide approximately 60% of the power for the evaporator fan and the condenser fan. Finally, the performance of the system is compared with that of the solid sorption refrigeration system. The refrigerating capacity of two systems is almost the same at the same operational condition. Therefore, the power generation process does not influence the refrigeration process. The exergy efficiency of the two systems is 0.076 and 0.047, respectively. The feasibility of the system is determined, which proves that this system is especially suitable for the exhaust waste heat recovery.

关键词： solid sorption     exhaust waste heat     combined cooling and power system     exergy efficiency    

HTML PDF 收藏

Nexus between polymer support and metal oxide nanoparticles in hybrid nanosorbent materials (HNMs) for sorption

Ryan C. SMITH,Jinze LI,Surapol PADUNGTHON,Arup K. SENGUPTA

《环境科学与工程前沿（英文）》 2015年 第9卷 第5期   页码 929-938 doi: 10.1007/s11783-015-0795-9

摘要： Metal oxide nanoparticles like hydrated ferric oxide (HFO) or hydrated zirconium oxide (HZrO) are excellent sorbents for environmentally significant ligands like phosphate, arsenic, or fluoride, present at trace concentrations. Since the sorption capacity is surface dependent for HFO and HZrO, nanoscale sizes offer significant enhancement in performance. However, due to their miniscule sizes, low attrition resistance, and poor durability they are unable to be used in typical plug-flow column setups. Meanwhile ion exchange resins, which have no specific affinity toward anionic ligands, are durable and chemically stable. By impregnating metal oxide nanoparticles inside a polymer support, with or without functional groups, a hybrid nanosorbent material (HNM) can be prepared. A HNM is durable, mechanically strong, and chemically stable. The functional groups of the polymeric support will affect the overall removal efficiency of the ligands exerted by the Donnan Membrane Effect. For example, the removal of arsenic by HFO or the removal of fluoride by HZrO is enhanced by using anion exchange resins. The HNM can be precisely tuned to remove one type of contaminant over another type. Also, the physical morphology of the support material, spherical bead versus ion exchange fiber, has a significant effect on kinetics of sorption and desorption. HNMs also possess dual sorption sites and are capable of removing multiple contaminants, namely, arsenate and perchlorate, concurrently.

关键词： ion exchange     sorption     arsenic     perchlorate     fluoride    

HTML PDF 收藏

Contributions of adsorption, bioreduction and desorption to uranium immobilization by extracellular polymeric substances

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1707-z

摘要：

● EPS immobilizes U(VI) via adsorption, bioreduction and desorption.

关键词： Adsorption     Bioreduction     Desorption     Kinetics     Isotherm     Uranium    

HTML PDF 收藏

Diphenylarsinic acid sorption mechanisms in soils using batch experiments and EXAFS spectroscopy

Meng Zhu, Yongming Luo, Ruyi Yang, Shoubiao Zhou, Juqin Zhang, Mengyun Zhang, Peter Christie, Elizabeth L. Rylott

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1237-x

摘要： DPAA sorption data was found to fit the Freundlich equation. Kf was significantly positive correlated with oxalate-extractable Fe2O3. Ligand exchange was the main mechanism for DPAA sorption on soils. Bidentate binuclear and monodentate mononuclear DPAA bonds were identified. Diphenylarsinic acid (DPAA) is a phenyl arsenic compound derived from chemical warfare weapons. Macroscopic and microscopic work on DPAA sorption will provide useful information in predicting the partitioning and mobility of DPAA in the soil-water environment. Here, batch experiments and extended X-ray absorption fine structure (EXAFS) spectroscopy were used to investigate the sorption mechanisms of DPAA. The DPAA sorption data from 11 soil types was found to fit the Freundlich equation, and the sorption capacity, Kf, was significantly and positively correlated with oxalate-extractable Fe2O3. The Kf values of eight of the 11 untreated soils (1.51–113.04) significantly decreased upon removal of amorphous metal (hydr)oxides (0.51–13.37). When both amorphous and crystalline metal (hydr)oxides were removed from the untreated soils, the Kf values either decreased or slightly increased (0.65–3.09). Subsequent removal of soil organic matter from these amorphous and crystalline metal (hydr)oxide-depleted samples led to further decreases in Kf to 0.02–1.38, with only one exception (Sulfic Aquic-Orthic Halosols). These findings strongly suggest that ligand exchange reactions with amorphous metal (hydr)oxides contribute most to DPAA sorption on soils. EXAFS data provide further evidence that DPAA primarily formed bidentate binuclear (2C) and monodentate mononuclear (1V) coring-sharing complexes with As-Fe distances of 3.34 and 3.66 Å, respectively, on Fe (hydr)oxides. Comparison of these results with earlier studies suggests that 2C and 1V complexes of DPAA may be favored under low and high surface coverages, respectively, with the formation of 1V bonds possibly conserving the sorption sites or decreasing the steric hindrance derived from phenyl substituents.

关键词： Diphenylarsinic acid     EXAFS     Fe (hydr)oxide     Soil organic matter     Sorption mechanism    

HTML PDF 收藏

Effects of different sediment fractions on sorption of galaxolide

Lixia JIN, Mengchang HE, Jinghuan ZHANG

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 59-65 doi: 10.1007/s11783-010-0259-1

摘要： Sorption isotherms of galaxolide (HHCB) of different fractions from two sediments with different mineral and organic carbon contents were determined to compare HHCB sorption behavior and contribution to the total sorption. The HHCB sorption isotherms that used the batch equilibration method were studied on different sediments of different fractions. The sorption isotherms of 600°C heating fractions were detailed using the linear model, while the other fractions were nonlinear and fitted well with the Freundlich model. The dissolved organic carbon (DOC) removed, NaOH extracted, and 375°C heating fractions showed more nonlinear sorption than the original sediments, which suggested more heterogeneous sorption sites in these fractions. Compared to the original sediments, the 375°C heating fractions had higher carbon-normalized distribution coefficient ( ) values, indicating a higher sorption affinity for HHCB. Among the different sediment fractions, the contribution of the 600°C heating fractions to the overall sorption were the lowest (<20%), while the 375°C heating fractions were the highest (up to 85%).

关键词： galaxolide (HHCB)     sorption     organic carbon     sediment     carbon-normalized distribution coefficient (Koc)    

HTML PDF 收藏

Contribution of black carbon to nonlinearity of sorption and desorption of acetochlor on sediment

Jianqiu LIU, Yaobin ZHANG, Hong CHEN, Yazhi ZHAO, Xie QUAN

《环境科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 69-74 doi: 10.1007/s11783-008-0076-y

摘要： In order to investigate the contribution of various black carbon (BC) contents to nonlinearity of sorption and desorption isotherms for acetochlor on sediment, equilibrium sorption and desorption isotherms were determined to measure sorption and desorption of acetochlor in sediment amended with various amounts of BC. In this paper, two types of BC referred to as BC400 and BC500 were prepared at 400°C and 500°C, respectively. Higher preparation temperature facilitated the formation of micropores on BC to enhance its sorption capacity. Increase of the BC content obviously increased the sorption amount and reduced the desorption amount for acetochlor. When the BC500 contents in total organic carbon (TOC) increased from 0 to 60%, Freundlich sorption coefficient ( ) increased from 4.07 to 35.74, and desorption hysteresis became gradually obvious. When the content of BC in TOC was lower than 23%, the sorption isotherm had a significant linear correlation ( = 0.05). In case of desorption, a significant nonlinear change could be observed when the content of BC was up to 13%. Increase of BC content in the sediment would result in shifting the sorption-desorption isotherms from linearity to nonlinearity, which indicated that contribution of BC to nonlinear adsorption fraction became gradually remarkable.

关键词： black carbon (BC)     sorption     desorption     sediment    

HTML PDF 收藏

Phenanthrene sorption to environmental black carbon in sediments from the Song-Liao watershed (China)

Jinghuan ZHANG, Mengchang HE, Chunye LIN, Ke SUN, Bin MEN, John L. ZHOU,

《环境科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 434-442 doi: 10.1007/s11783-009-0150-0

摘要： Black carbon (BC) in ten contaminated sediments from the Song-Liao watershed, NE China, was isolated upon treatments using a combustion method at 375°C, and the isolates’ sorption isotherms for phenanthrene (Phen) were determined. All sorption isotherms were nonlinear and fitted well by the Freundlich model. A negative relation was found between Freundlich sorption nonlinearity parameter ( values) and BC/total organic carbon (TOC) content of the original sediments (=0.687, <0.01), indicating the dominance of BC in Phen sorption nonlinearity. The BC isolates from this industrialized region had values of 0.342 to 0.505 and log values of 6.02 to 6.42(μg·kg·OC)/(μg·L) for Phen. At a given , the BC had higher value than the original sediments, revealing a higher sorption capacity for BC. BC was responsible for 50.0% to 87.3% of the total sorption at =0.05 , clearly indicating the dominance of BC particles in overall sorption of Phen by sediments.

关键词： phenanthrene     sorption     black carbon     sediment     Song-Liao watershed    

HTML PDF 收藏

Selective sorption of perfluorooctane sulfonate on molecularly imprinted polymer adsorbents

Shubo DENG, Danmeng SHUAI, Qiang YU, Jun HUANG, Gang YU

《环境科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 171-177 doi: 10.1007/s11783-009-0017-4

摘要： Perfluorooctane sulfonate (PFOS), as a potential persistent organic pollutant, has been widely detected in water environments, and has become a great concern in recent years. PFOS is very stable and difficult to decompose using conventional techniques. Sorption may be an attractive method to remove it from water. In this study, the molecularly imprinted polymer (MIP) adsorbents were prepared through the polymerization of 4-vinylpyridine under different preparation conditions in order to remove perfluorooctane sulfonate (PFOS) from water. The MIP adsorbents using perfluorooctanoic acid (PFOA) as the template had good imprinting effects and could selectively remove PFOS from aqueous solution. The sorption behaviors including sorption kinetics, isotherms, and effect of pH, salt, and competitive anions were investigated. Experimental results showed that the sorption of PFOS on the MIP adsorbents was very fast, pH-dependent, and highly selective. The achieved fast sorption equilibrium within 1 h was attributed to the surface sorption on the fine adsorbents. The sorption isotherms showed that the sorption selectivity of PFOS on the MIP adsorbents decreased at high PFOS concentrations, which may be due to the double-layer sorption and the formation of PFOS micelles on the sorbent surface. The sorption of PFOS on the MIP adsorbents was mainly dominated by the electrostatic interaction between the protonated vinylpyridine on the adsorbent surface and the anionic PFOS. The prepared MIP adsorbents can potentially be applied in water and wastewater treatment for selective removal of PFOS.

关键词： perfluorooctane sulfonate (PFOS)     molecularly imprinted polymer (MIP) adsorbents     selective sorption     electrostatic interaction    

HTML PDF 收藏

Multi-stage ammonia production for sorption selective catalytic reduction of NO

Chen ZHANG, Guoliang AN, Liwei WANG, Shaofei WU

《能源前沿（英文）》 2022年 第16卷 第5期   页码 840-851 doi: 10.1007/s11708-021-0797-1

摘要： Sorption selective catalytic reduction of nitrogen oxides (NOx) (sorption-SCR) has ever been proposed for replacing commercial urea selective catalytic reduction of NOx (urea-SCR), while only the single-stage sorption cycle is hitherto adopted for sorption-SCR. Herein, various multi-stage ammonia production cycles is built to solve the problem of relative high starting temperature with ammonia transfer (AT) unit and help detect the remaining ammonia in ammonia storage and delivery system (ASDS) with ammonia warning (AW) unit. Except for the single-stage ammonia production cycle with MnCl2, other sorption-SCR strategies all present overwhelming advantages over urea-SCR considering the much higher NOx conversion driven by the heat source lower than 100°C and better matching characteristics with low-temperature catalysts. Furthermore, the required mass of sorbent for each type of sorption-SCR is less than half of the mass of AdBlue for urea-SCR. Therefore, the multifunctional multi-stage sorption-SCR can realize compact and renewable ammonia storage and delivery with low thermal energy consumption and high NOx conversion, which brings a bright potential for efficient commercial de-NOx technology.

关键词： selective catalytic reduction (SCR)     nitrogen oxides (NOx)     ammonia     composite sorbent     chemisorption    

HTML PDF 收藏

Immobilized

Pei MA, Dan ZHANG

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 498-508 doi: 10.1007/s11783-012-0429-4

摘要： To investigate the potential use of ( ) residue for Cd adsorption, poly alcohol Na alginate (PVA) was applied to immobilize it. The parameters including contact time, pH, adsorbent dosages, and coexisting metal ions were studied. The suitable pH for immobilized was 4–7 wider than that for raw (pH 6–7). In the presence of Pb concentration varying from 0 to 30 mg·L , the Cd adsorption ratios declined by 6.71% and 47.45% for immobilized and raw , respectively. While, with the coexisting ion Cu concentration varied from 0 to 30 mg·L , the Cd adsorption ratios declined by 12.97% and 50.56% for immobilized and raw , respectively. The Cd adsorption isotherms in single–metal and dual-metal solutions were analyzed by using Langmuir, Freundlich, and Dubinin–Radushkevich models. The Cd adsorption capacities ( ) in single-metal solution were 6.448 mg·L and 2.832 mg·L for immobilized and raw , respectively. The of immobilized were 1.850 mg Cd·g in Cd + Pb solution and 3.961 mg Cd·g in Cd + Cu solution, respectively. The Cd adsorption processes subjected to both adsorbents follow pseudo-second-order model. Mechanism study showed the functional group of was –OH, –NH, –CO, and PVA played an important role in metal adsorbing. Mining wastewater treatment test showed that PVA–SA-immobilized was effective in mixed pollutant treatment even for wastewater containing metal ions in very low concentration.

关键词： immobilization     Lentinus edodes residue     competitive adsorption     isotherm    

HTML PDF 收藏

标题 作者 时间 类型 操作

Performance and mechanism for cadmium and lead adsorption from water and soil by corn straw biochar

Tong Chi,Jiane Zuo,Fenglin Liu

期刊论文

Major applications of heat pipe and its advances coupled with sorption system: a review

Yang YU, Guoliang AN, Liwei WANG

期刊论文

Preparation of adsorptive nanoporous membrane using powder activated carbon: Isotherm and thermodynamic

Majid Peyravi

期刊论文

Sorption mechanisms of diphenylarsinic acid on natural magnetite and siderite: Evidence from sorption

期刊论文

Thermodynamic study on dynamic water and organic vapor sorption on amorphous valnemulin hydrochloride

Jinbo OUYANG, Jingkang WANG, Yongli WANG, Qiuxiang YIN, Hongxun HAO

期刊论文

Simulation and experiments on a solid sorption combined cooling and power system driven by the exhaust

Peng GAO, Liwei WANG, Ruzhu WANG, Yang YU

期刊论文

Nexus between polymer support and metal oxide nanoparticles in hybrid nanosorbent materials (HNMs) for sorption

Ryan C. SMITH,Jinze LI,Surapol PADUNGTHON,Arup K. SENGUPTA

期刊论文

Contributions of adsorption, bioreduction and desorption to uranium immobilization by extracellular polymeric substances

期刊论文

Diphenylarsinic acid sorption mechanisms in soils using batch experiments and EXAFS spectroscopy

Meng Zhu, Yongming Luo, Ruyi Yang, Shoubiao Zhou, Juqin Zhang, Mengyun Zhang, Peter Christie, Elizabeth L. Rylott

期刊论文

Effects of different sediment fractions on sorption of galaxolide

Lixia JIN, Mengchang HE, Jinghuan ZHANG

期刊论文

Contribution of black carbon to nonlinearity of sorption and desorption of acetochlor on sediment

Jianqiu LIU, Yaobin ZHANG, Hong CHEN, Yazhi ZHAO, Xie QUAN

期刊论文

Phenanthrene sorption to environmental black carbon in sediments from the Song-Liao watershed (China)

Jinghuan ZHANG, Mengchang HE, Chunye LIN, Ke SUN, Bin MEN, John L. ZHOU,

期刊论文

Selective sorption of perfluorooctane sulfonate on molecularly imprinted polymer adsorbents

Shubo DENG, Danmeng SHUAI, Qiang YU, Jun HUANG, Gang YU

期刊论文

Multi-stage ammonia production for sorption selective catalytic reduction of NO

Chen ZHANG, Guoliang AN, Liwei WANG, Shaofei WU

期刊论文

Immobilized

Pei MA, Dan ZHANG

期刊论文